| EP# | Title | Original airdate | English airdate |
| 21 | "Enter! The World of the Shinigami"
| March 1, 2005 | February 2, 2007 |
| 22 | "The Man Who Hates Shinigami"
| March 8, 2005 | February 9, 2007 |
| 23 | "The Sentence of Rukia, Before the 14th Day"
| March 15, 2005 | February 16, 2007 |
| 24 | "Assemble! The 13 Divisions"
| March 22, 2005 | February 23, 2007 |
| 25 | "Penetrate the Centre with an Enormous Bombshell?"
| March 29, 2005 | March 2, 2007 |
| 26 | "Formation! The Worst Tag"
| April 5, 2005 | March 9, 2007 |
| 27 | "Release the Death Blow!"
| April 12, 2005 | March 25, 2007 |
| 28 | "Orihime Is Being Targeted"
| April 19, 2005 | April 8, 2007 |
| 29 | "Breakthrough! The Shinigami's Encompassing Net"
| April 26, 2005 | April 15, 2007 |
| 30 | "Renji's Confrontation"
| May 3, 2005 | April 22, 2007 |
| 31 | "The Resolution to Kill"
| May 10, 2005 | April 29, 2007 |
| 32 | "Stars and the Stray"
| May 17, 2005 | May 6, 2007 |
| 33 | "Miracle! The Mysterious New Hero"
| May 26, 2005 | May 13, 2007 |
| 34 | "Tragedy of Dawn"
| June 1, 2005 | May 20, 2007 |
| 35 | "Assassination of Aizen! The Darkness which Approaches"
| June 7, 2005 | May 27, 2007 |
| 36 | "Kenpachi Zaraki Approaches!"
| June 14, 2005 | June 9, 2007 |
| 37 | "Reason of the Fist"
| June 21, 2005 | June 17, 2007 |
| 38 | "Desperation! The Broken Zangetsu"
| June 28, 2005 | June 24, 2007 |
| 39 | "The Man of Immortality"
| July 5, 2005 | July 1, 2007 |
| 40 | "The Shinigami whom Ganju Met"
| July 12, 2005 | July 8, 2007 |
| 41 | "Reunion, Ichigo and Rukia"
| July 19, 2005 | July 15, 2007 |
