| EP# | Title | Original airdate | English airdate |
| 230 | "A New Enemy! The Materialization of Zanpakutō"
| July 28, 2009 | — |
| 231 | "Byakuya, Disappearing with the Cherry Blossoms"
| August 4, 2009 | — |
| 232 | "Sode no Shirayuki vs. Rukia! Confused Heart"
| August 11, 2009 | — |
| 233 | "Zangetsu Becomes an Enemy"
| August 18, 2009 | — |
| 234 | "Renji Surprised?! The Two Zabimarus"
| August 25, 2009 | — |
| 235 | "Clash! Hisagi vs. Kazeshini"
| September 1, 2009 | — |
| 236 | "Release! The New Getsuga Tenshō"
| September 8, 2009 | — |
| 237 | "Soi Fon, Surrounding the Zanpakutō"
| September 15, 2009 | — |
| 238 | "Friendship? Hatred? Haineko & Tobiume"
| September 22, 2009 | — |
| 239 | "The Awakening Hyōrinmaru! Hitsugaya's Fierce Fight"
| September 29, 2009 | — |
| 240 | "Byakuya's Betrayal"
| October 6, 2009 | — |
| 241 | "For the Sake of Pride! Byakuya vs. Renji"
| October 13, 2009 | — |
| 242 | "Shinigami and Zanpakutō, Total Sortie"
| October 20, 2009 | — |
| 243 | "One-to-One Fight! Ichigo vs. Senbonzakura"
| October 27, 2009 | — |
| 244 | "The Long Awaited... Kenpachi Appears!"
| November 3, 2009 | — |
| 245 | "Pursue Byakuya! The Confused Gotei Divisions"
| November 10, 2009 | — |
| 246 | "Special Mission! Rescue Captain Commander Yamamoto!"
| November 17, 2009 | — |
| 247 | "Deceived Shinigami! The World Collapse Crisis"
| November 24, 2009 | — |
| 248 | "Dragon of Ice and Dragon of Flame! The Strongest Showdown!"
| December 1, 2009 | — |
| 249 | "Senbonzakura's Bankai! Offense and Defense of the Living World"
| December 8, 2009 | — |
| 250 | "That Man, for the Sake of the Kuchiki"
| December 15, 2009 | — |
| 251 | "Dark History! The Worst Shinigami Is Born"
| December 22, 2009 | — |
| 252 | "Byakuya, the Truth Behind His Betrayal"
| January 5, 2010 | — |
| 253 | "Muramasa's True Identity Revealed"
| January 12, 2010 | — |
| 254 | "Byakuya and Renji, the 6th Division Returns"
| January 19, 2010 | — |
| 255 | "Final Chapter - Zanpakutō The Alternate Tale"
| January 26, 2010 | — |
